期刊
HELVETICA CHIMICA ACTA
卷 102, 期 3, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/hlca.201900002
关键词
Aza-ortho-xylylene; isocyanides; 2-aminoindole; N-(ortho-chloromethyl)aryl amide; cycloaddition
资金
- EPFL (Switzerland)
- Swiss National Science Foundation [SNSF 20020-155973]
Reaction of substituted o-aminobenzyl chlorides with isocyanides in the presence of a weak base (NaHCO3) at room temperature afforded the diversely functionalized 2-aminoindoles in good to excellent yields. A formal [4+1] cycloaddition of the insitu generated aza-ortho-xylylenes with isocyanides accounted for the reaction outcome.
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