期刊
FUEL PROCESSING TECHNOLOGY
卷 184, 期 -, 页码 57-64出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.fuproc.2018.11.009
关键词
Co-combustion; Pickling sludge; Gaseous pollutant emission; Heavy metal leaching
资金
- Innovative Research Groups of the National Natural Science Foundation of China [51621005]
- National Natural Science Foundation of China [51676172]
- Fundamental Research Funds for the Central Universities [2018FZA4010, 2016FZA4010]
- Special Fund for the National Environmental Protection Public Welfare Program [201209023-4]
- Program of Introducing Talents of Discipline to University [B08026]
Co-combustion of Shenmu coal and pickling sludge was carried out in a pilot scale drop-tube furnace. The effect of different pickling sludge amounts on the NOx, SO2, HCl, HF, PCDD/Fs and gaseous heavy metals emissions and fly ash behaviors was studied. The burnout section furnace temperature was 1250 degrees C, and the pickling sludge amount ranged from 0 to 20 wt%. The result indicates that the co-combustion of < 20 wt% pickling sludge did not reduce the combustion efficiency. With increasing pickling sludge amount in the blended fuels, NOx and HCl emission concentrations were basically stable; however, those of SO2 and HF increased obviously. The total TEQ of PCDD/Fs emission was basically positively correlated to the sludge amount in the blended fuels, and the gaseous heavy metals emissions also increased obviously with the addition of sludge. To meet the national standard (GB18484-2001) on heavy metals emissions, the pickling sludge amount used in co-combustion must be < 10 wt%. According to national standard (GB 16889-2008), because of the high leaching concentrations of heavy metals Cr, Ni, Cu and Pb, the co-combustion fly ash needs further treatment before being landfilled disposal as common waste.
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