期刊
FUEL
卷 237, 期 -, 页码 276-282出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.fuel.2018.10.023
关键词
Flow improvers; Asphaltene; Hydrogen bond; Mechanism
资金
- State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation (Southwest Petroleum University) [PLN1312]
- Scientific Research Starting Project of Southwest Petroleum University [2015QHZ015]
- Opening Project of Oil & Gas Field Applied Chemistry Key Laboratory [YQKF201401]
A series of chemical products with characteristic groups in molecular structures were synthesized as novel flow improvers (FIs) for heavy asphaltenic crude oil. The rheological measurement results showed that the FI-5 could behave the better performance in improving fluidity of heavy oil than FI-2 due to the former could form stronger hydrogen bonds with asphaltene in oil, which was confirmed through Fourier transform infrared spectroscopy (FTIR) and energy of simulating studies. Furthermore, X-ray diffraction (XRD) analysis results demonstrated that two products altered asphaltene structure at different degree through hydrogen bonding interaction, and the aggregation-dispersion effect of FIs on asphaltene were respectively obtained through scanning electron microscope (SEM), which beneficially weakened the stable structure of asphaltene in the heavy crude oil system. Hence, the mechanisms were tried to propose that could explain the phenomenon in rheological measurement why FI-2 was not as good as FI-5 in improving fluidity of heavy oil. Results also indicated that the asphaltene content and aggregation structure in oils were vital parameters for its viscosity.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据