期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2019, 期 21, 页码 3401-3405出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201900153
关键词
Ball-mill; Mechanochemistry; Pillar[5]arene; Rotaxanes; Supramolecular chemistry
资金
- ANR [ANR-17-CE07-0012-01]
- International Center for Frontier Research in Chemistry
- LabEx Chimie des Systemes Complexes
Pillar[5]arene-containing [2]rotaxanes have been efficiently prepared under solvent-free conditions. Specifically, solid-to-solid ball-milling of primary or secondary amine reagents with the inclusion complex resulting from the association of dodecanedioyl dichloride and a pillar[5]arene derivative provided the corresponding diamide [2]rotaxanes in good to excellent yields. Importantly, [2]rotaxanes difficult or even impossible to prepare under classical reaction conditions in solution, are now easily obtained.
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