期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2019, 期 15, 页码 2635-2638出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201900128
关键词
Palladium; Ligands; Alkenes; Allylic oxidation; Regioselectivity
资金
- National Natural Science Foundation of China [21676252]
- Collaborative Innovation Center of Yangtze River Delta Region Green Pharmaceuticals
First-time use of a palladium(II)-thiadiazole catalyst in the allylic oxidation of terminal olefins to linear allylic acetates. Employing this strategy, a range of allylic esters (20 examples) were synthesized in 43 % to 80 % yield with excellent regio- and stereoselectivities.
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