期刊
CORROSION SCIENCE
卷 148, 期 -, 页码 213-227出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.corsci.2018.12.020
关键词
Stainless steel; Surface oxidation; Crack tip oxidation; Stress corrosion cracking; Transmission electron microscopy
资金
- National Science and Technology Major Project of China [2011ZX06004]
- China Scholarship Council
- EPSRC [EP/K040375/1, EP/N010868/1, EP/R009392/1]
- EPSRC [EP/R009392/1, EP/N010868/1, EP/K040375/1, EP/J013501/1] Funding Source: UKRI
Oxidation and stress corrosion cracking (SCC) of 316L stainless steel were studied in simulated pressurized water reactor primary water. Surface, crack flank, and crack tip oxides were analyzed and compared by high-resolution characterization, including oxidation state mapping. All oxides were found to have a triplex structure, although of different dimensions and composition, revealing the effects of local water chemistry and applied stress. The higher oxidation rate at the crack tip could be explained due to the existence of a higher dislocation density, higher level of stress and cation unavailability from the environment. The implications to SCC mechanisms are discussed.
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