期刊
COORDINATION CHEMISTRY REVIEWS
卷 382, 期 -, 页码 85-102出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2018.11.011
关键词
Water soluble; Titanium oxide; Clusters; Polyoxometalates; Nanocrystals
资金
- Israel Science Foundation [170/17]
- Council for Higher Education of Israel
The water-soluble titanium-oxide structures covered in this review span a continuum from molecular clusters to colloidal nanocrystals. Here, a deliberate distinction is made between titanium clusters and nanoparticles with organic ligands, soluble in organic solvents, and related structures prepared and soluble in water. This distinction is made in response to rapid developments in three areas covered in this article: small titanium-oxide clusters prepared at low pH values in water, heterpolytungstate macroanions with high-nuclearity titanium-oxide cores, and polyoxometalate complexes of anatase-phase TiO2. The latter nanostructures occupy a unique position between polyoxometalate macroanions and traditional colloidal TiO2. As such, the progressively larger water-soluble titanium-oxide structures covered in the three main sections of this review establish a continuum that begins to blur the longstanding divide between molecular and colloid science. (C) 2018 Elsevier B.V. All rights reserved.
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