期刊
CHEMSUSCHEM
卷 12, 期 13, 页码 3028-3031出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201900360
关键词
alkenes; catalysis; diamines; iodine; oxidation
资金
- Ministerio de Economía, Industria y Competitividad, Gobierno de España [CTQ2017-88496R] Funding Source: Medline
2,6-Disubstituted iodoarenes bearing amide-functionalized side arms are reported as new structures in redox-active iodine(I/III) catalysis. In combination with bis-sulfonimides as nitrogen sources and 3-chloroperbenzoic acid (mCPBA) as benign terminal oxidant they catalyze the vicinal diamination of styrenes. The obtained reactivity and selectivity outperform other iodoarene catalyst candidates. This protocol provides a sustainable alternative to previous related protocols for diamination that are based on stoichiometric iodine(III) reagents.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据