期刊
CHEMOSPHERE
卷 218, 期 -, 页码 391-401出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.chemosphere.2018.11.080
关键词
Carbon nanotubes; Chitosan; Magnetic separation; Chromium removal
资金
- Fundacao de Amparo a Pesquisa do Estado de Minas Gerais (FAPEMIG) [APQ-00445-14]
- Conselho Nacional de Desenvolvimento Cientifico and Tecnologico (CNPq)
An adsorbent in the form of a CLCh/MWCNT/Fe film was prepared using multiple walled carbon nano-tubes (MWCNT) doped with magnetic iron oxide and deposited in crosslinked chitosan (CLCh). The CLCh/ MWCNT/Fe was characterized by Inductively Coupled Plasma Mass Spectrometry (ICP-MS), nitrogen (N-2) adsorption/desorption, X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Energy Dispersive Spectrometry (EDS), Infrared Spectroscopy (IR) and Raman Spectroscopy. The CLCh/MWCNT/Fe film presented a maximum adsorption capacity for Cr(III) of 66.25 mg/g (150 min) and for Cr(VI) of 449.30 mg/g (60 min) at 25 degrees C. The CLCh/MWCNT/Fe can be easily removed from the aqueous solution by a mechanical separation or by magnetization due to its magnetic properties. In ten consecutive reutilization adsorption cycles the CLCh/MWCNT/Fe film presented efficiency losses of only 12% and 6% for the removal of Cr(III) and Cr(VI), respectively. (C) 2018 Elsevier Ltd. All rights reserved.
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