期刊
CHEMISTRY OF MATERIALS
卷 31, 期 6, 页码 2106-2113出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.chemmater.9b00001
关键词
-
资金
- INSPIRE, DST
- DST Nanomission
- Deutsche Forschungsgemeinschaft (DFG) [ZE 1010/5-1]
- Alexander von Humboldt Foundation
- JNCASR
Crystalline materials with ultralow thermal conductivity are essential for thermal barrier coating and thermoelectric energy conversion. Nontoxic n-type bulk cubic AgBiS2 exhibits exceptionally low lattice thermal conductivity (kappa(lat)) of 0.68-0.48 W/m K in the temperature range of 298-820 K, which is near the theoretical minimum (kappa(min)). The low kappa(lat) is attributed to soft vibrations of predominantly Ag atoms and significant lattice anharmonicity because of local structural distortions along the [011] direction, arising because of the stereochemical activity of the 6s(2) lone pair of Bi, as suggested by pair distribution function analysis of the synchrotron X-ray scattering data. The low-temperature heat capacity of AgBiS2 shows a broad hump because of the Ag-induced low-energy Einstein modes as also suggested from phonon dispersion calculated by first-principle density functional theory. Low-energy optical phonons contributed by Ag and Bi strongly scatter heat-carrying acoustic phonons, thereby decreasing the kappa(lat) to a low value. A maximum thermoelectric figure of merit of similar to 0.7 is attained at 820 K for bulk spark plasma-sintered n-type AgBiS2.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据