期刊
CHEMISTRY LETTERS
卷 48, 期 6, 页码 510-512出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.190074
关键词
Cyclization; Rhodium carbenoids; Triazoles
资金
- MEXT [15H05756, 16K05694]
- JSPS
- Grants-in-Aid for Scientific Research [15H05756, 16K05694] Funding Source: KAKEN
A rhodium-catalyzed cyclization reaction of 4-acyl-1-sulfonyl-1,2,3-triazoles possessing a phenyl ring is reported. Generated acceptor/ acceptor carbenoids undergo cyclization by reacting either with a phenyl ring through electrophilic aromatic substitution or with a benzylic C-H bond through insertion depending on the length of the carbon chain.
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