期刊
CHEMISTRY LETTERS
卷 48, 期 2, 页码 133-136出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.180888
关键词
Conjugated macrocyclic molecule; Quinoline; Isocyanide-acetylene cyclization reaction
A conjugated macrocyclic molecule incorporating two m-diethynylene-phenylene-bridged quinoline moieties was synthesized via isocyanide-acetylene cyclization and Pd/Cu-catalyzed Sonogashira cross-coupling reactions. X-ray crystal analysis and DFT calculation revealed that the new macrocyclic molecule has a rigid parallelogram structure. The photophysical and electrochemical properties were studied by several spectral analyses, and were rationalized by DFT calculations.
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