期刊
CHEMICAL ENGINEERING JOURNAL
卷 357, 期 -, 页码 220-225出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2018.09.142
关键词
Anode material; CoS; MXene; Nanoparticle; Sodium ion battery
资金
- National Natural Science Foundation of China [21773188]
- Fundamental Research Funds for the Central Universities [XDJK2017A002, XDJK2017B048]
- Program for Innovation Team Building at Institutions of Higher Education in Chongqing [CXTDX201601011]
Electrochemical performance of Ti3C2 MXene sheet is restricted by the modest specific capacity and self-re-stacking. To conquer the defects, we designed cobalt sulfide and Ti3C2 MXene flake composite (CoS/MXene) with heterolayered architecture, in which ultrafine CoS nanoparticles (similar to 6 nm) were anchored on MXene flakes. In this structure, the role of MXene is similar to printed circuit board, which providing conducive network. As anode for sodium ion batteries, CoS/MXene electrode delivers a high reversible capacity of 267 mA h g(-1 )after 1700 cycles at 2 A g(-1) with an extreme low capacity decay rate of only similar to 0.0072% per cycle, and an outstanding rate performance with 272 mA h g(-1) at 5 A g(-1).
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