期刊
CHEMICAL ENGINEERING JOURNAL
卷 359, 期 -, 页码 1652-1658出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2018.10.225
关键词
NiCo2S4; Nanowire arrays; Urea electrooxidation; Electrocatalyst; Fuel cell
资金
- National Natural Science Foundation of China [51672056]
- China Postdoctoral Science Foundation [2018M630307]
- Fundamental Research Funds for the Central Universities [HEUCF181007]
- Heilongjiang Postdoctoral Scientific Research Developmental Fund [LBH-Q16044]
A 3D NiCo2S4 nanowire arrays directly grown on Ni foam electrode (NiCo2S4/NF) is prepared by two-step simple hydrothermal process. The morphology and phase composition of NiCo2S4/NF are characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). As expected, in the following electrocatalytic measurement, the binder-free, self-made NiCo2S4/NF electrode exhibits much higher catalytic activity, lower onset potential, better stability and greater tolerance towards urea electrooxidation compared with the Ni3S2/NF electrode synthesized under the same reaction conditions. The NiCo2S4/NF electrode delivers a current density of 720 mA cm(-2) at 0.18 V (vs. Ag/AgCl) in a solution containing 5 mol L-1 KOH and 0.33 mol L-1 urea. The impressive electrocatalytic activity of the NiCo2S4/NF catalyst is largely ascribed to its distinctive structure, which exposes more electrochemical active sites at the electrode-electrolyte interface. Besides, the high intrinsic electronic conductivity also largely boosts the charge transfer rates for urea electrooxidation. The results demonstrate that the NiCo2S4/NF electrode showing a beneficial application prospect in the wastewater treatment and direct urea fuel cells.
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