期刊
CERAMICS INTERNATIONAL
卷 45, 期 3, 页码 3591-3599出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2018.11.019
关键词
Co3S4 nanosheets; 3D hierarchical structure; MWCNT; Sodium-ion battery; Anode material
资金
- National Natural Science Foundation of China [51572078, 51772086, 51872087]
- Natural Science Foundation of Hunan Province [2018JJ2038]
- Student National SIT Innovation Program
In this work, Co3S4/CNTs three-dimensional hierarchical microstructure has been synthesized through a facile sulfidation method with Co3O4/CNTs as precursor. Particularly, by controlling hydrothermal time, the optimized Co3S4/CNTs-9 composite consists of ultrathin and rich mesoporous Co3S4 nanosheets (< 10 nm) with CNTs firmly intertwined inside microstructures. Benefitting from the porous and robust secondary-structure, as well as the intertwined CNTs among ultrathin active materials Co3S4 nanosheets, Co3S4/CNTs-9 electrode provides fast efficient ways of ion and electron transportation. As a result, it exhibits an excellent rate performance. Charge capacity retention at 1 Ag-1 is up to 80% compared with 0.1 Ag-1. The enhanced extrinsic pseudocapacitive contribution is confirmed at higher rate through the cyclic voltammetry analysis at different scan rates of Co3S4/CNTs-9 electrode. Importantly, Co3S4 electrode also exhibits a high initial coulombic efficiency of 82.89%, which suggests that Co3S4 is a promising anode candidate for sodium-ion batteries.
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