期刊
APPLIED SURFACE SCIENCE
卷 470, 期 -, 页码 360-367出版社
ELSEVIER
DOI: 10.1016/j.apsusc.2018.11.151
关键词
CuCo2O4 nanosheets; Electrodeposition; Supercapacitor; Electrocatalyst; Oxygen evolution reaction
类别
资金
- National Research Foundation (NRF) of Korea [2018R1A2B6007436, 2016R1A6A1A03012877, 2016R1A3B1908249, 2018R1D1A1A09083859, 2018R1D1A1B07049046]
- National Research Foundation of Korea [2018R1D1A1A09083859] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Efficient and low-cost multifunctional electrodes play a key role in improving the performance of energy conversion and storage devices. In this study, ultrathin nanoporous CuCo2O4 nanosheets are synthesized on a nickel foam substrate using electrodeposition followed by air annealing. The CuCo2O4 nanosheet electrode exhibits a high specific capacitance of 1473 F g(-1) at 1 A g(-1) with a capacity retention of similar to 93% after 5000 cycles in 3M KOH solution. It also works well as an efficient oxygen evolution reaction electrocatalyst, demonstrating an overpotential of 260 mV m 20 mA cm(-2) with a Tafel slope of similar to 64 mV dec(-1). in 1 M KOH solution, which is the lowest reported among other copper-cobalt based transition metal oxide catalysts. The catalyst is very stable > 20 mA cm(-2) for more than 25 h. The superior electrochemical performance of the CuCo2O4 nanosheet electrode is due to the synergetic effect of the direct growth of 2D nanosheet structure and a large electrochemically active surface area associated with nanopores on the CuCo2O4 nanosheet surface.
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