期刊
APPLIED CATALYSIS B-ENVIRONMENTAL
卷 241, 期 -, 页码 187-195出版社
ELSEVIER
DOI: 10.1016/j.apcatb.2018.09.032
关键词
Bi metal; Oxygen vacancy; Photocatalysis; Toxic intermediates inhibition; In situ DRIFTS
资金
- National Natural Science Foundation of China [21822601, 21777011, 21501016]
- National R&D Program of China [2016YFC0204702]
- Innovative Research Team of Chongqing [CXMGTD201602014]
- Natural Science Foundation of Chongqing [cstc2017jcyjBX0052]
- Plan for National Youth Talents of the Organization Department of the Central Committee
The design of highly efficient visible-light photocatalysts and the elucidation of decomposition mechanisms are the two key tasks in environmental remediation. Herein, we utilized theoretical calculations to design a Bi metal-based visible-light photocatalyst (Bi@BiOSi) with surface plasmon resonance (SPR) properties, showing that the unique electron delivery channel was formed at the Bi metal/Bi2O2SiO3 interface. The Bi@BiOSi nanosheets were used for photocatalytic removal of ppb-level atmospheric NO, with Bi metal-based SPR resulting in enhanced visible light capture and charge separation efficiency, whereas oxygen vacancy induced the formation of a midgap level and promoted O-2 activation. As a result, generation of superoxide and hydroxyl radicals over Bi@BiOSi was promoted, favoring photocatalytic NO removal. To elucidate the reaction mechanism, the products distribution during adsorption and photocatalytic NO oxidation on Bi@BiOSi were determined by in situ DRIFTS, which revealed that the increased production of reactive species inhibited the toxic intermediates (N2O4) formation and increased the selectivity of the NO-to-NO3- transformation via the synergy of oxygen vacancy and Bi metal. Thus, this work provides new insights into the design of non-noble metal-based photocatalysts and establishes a novel method of inhibiting the toxic intermediates production in photocatalysis for efficient and safe air purification.
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