期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 58, 期 18, 页码 5887-5890出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201900801
关键词
aldehydes; alkenes; coupling reactions; Neopeltolide; redox-neutral reactions
资金
- University of Vienna
- ERC (CoG VINCAT)
- FWF [P30226]
- Austrian Academy of Sciences (DOC Fellowship)
A flexible redox-neutral coupling of aldehydes and alkenes enables rapid access to stereotriads starting from a single stereocenter with perfect levels of enantio- and diastereoselectivity under mild conditions. The versatility of the method is highlighted by the installation of heteroatoms along the tether, which enables a route to structurally diverse building blocks. The formal synthesis of (+)-neopeltolide further demonstrates the synthetic utility of this approach.
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