期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 58, 期 17, 页码 5639-5642出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201900467
关键词
chain scission; cyclopolymers; mechanochemistry; mechanoresponsive polymers; olefination
资金
- Army Research Office [W911NF-15-1-0139]
- National Science Foundation [DMR-1452726]
- Camille and Henry Dreyfus Foundation
- Department of Energy
Herein we report the discovery of the intrinsic mechanochemical reactivity of vinyl-addition polynorbornene (VA-PNB), which has strained bicyclic ring repeat units along the polymer backbone. VA-PNBs with three different side chains were found to undergo ring-opening olefination upon sonication in dilute solutions. The sonicated polymers exhibited spectroscopic signatures consistent with conversion of the bicyclic norbornane repeat units into the ring-open isomer typical of polynorbornene made by ring-opening metathesis polymerization (ROMP-PNB). Thermal analysis and evaluation of chain-scission kinetics suggest that sonication of VA-PNB results in chain segments containing a statistical mixture of vinyl-added and ROMP-type repeat units.
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