期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 58, 期 17, 页码 5763-5768出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201811181
关键词
P-31 NMR spectroscopy; black phosphorus; covalent functionalization; Raman spectroscopy; reductive route
资金
- European Research Council (ERC) [742145 B-PhosphoChem, 2D-PnictoChem 804110]
- European Union [604391]
- Postdoctoral Junior Leader Fellowship Programme from la Caixa Banking Foundation [LCF/BQ/PI18/11630018]
- Deutsche Forschungsgemeinschaft (DFG) [FLAG-ERA AB694/2-1]
- Generalitat Valenciana [SEJI/2018/034]
- FAU (Emerging Talents Initiative grant) [WS16-17_Nat_04]
- DFG [SFB 953]
- Cluster of Excellence Engineering of Advanced Materials
- Free State of Bavaria (Research Network Solar Technologies go Hybrid)
- Alexander von Humboldt (AvH) Foundation
- MINECO (Spain) through the Excellence Unit Maria de Maeztu [MDM-2015-0538]
- MINECO (Spain) [CTQ2017-86735-P]
The chemical bulk reductive covalent functionalization of thin-layer black phosphorus (BP) using BP intercalation compounds has been developed. Through effective reductive activation, covalent functionalization of the charged BP by reaction with organic alkyl halides is achieved. Functionalization was extensively demonstrated by means of several spectroscopic techniques and DFT calculations; the products showed higher functionalization degrees than those obtained by neutral routes.
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