期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 58, 期 21, 页码 7062-7067出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201902679
关键词
electrochemistry; energy storage; oxygen redox chemistry; vanadium redox chemistry; zinc-ion batteries
资金
- National Natural Science Foundation of China [51822205, 21573116, 21875121]
- Ministry of Science and Technology of China [2017YFA0206701]
- Ministry of Education of China [B12015]
- Young Thousand Talents Program
Rechargeable aqueous zinc-ion batteries (ZIBs) are promising energy-storage devices owing to their low cost and high safety. However, their energy-storage mechanisms are complex and not well established. Recent energy-storage mechanisms of ZIBs usually depend on cationic redox processes. Anionic redox processes have not been observed owing to the limitations of cathodes and electrolytes. Herein, we describe highly reversible aqueous ZIBs based on layered VOPO4 cathodes and a water-in-salt electrolyte. Such batteries display reversible oxygen redox chemistry in a high-voltage region. The oxygen redox process not only provides about 27% additional capacity, but also increases the average operating voltage to around 1.56V, thus increasing the energy density by approximately 36%. Furthermore, the oxygen redox process promotes the reversible crystal-structure evolution of VOPO4 during charge/discharge processes, thus resulting in enhanced rate capability and cycling performance.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据