期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 58, 期 19, 页码 6244-6249出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201900084
关键词
carbon nanoring; fullerenes; host-guest systems; photocurrent; time-resolved spectroscopy
资金
- National Key Research and Development Program of China [2017YFA0402800]
- National Natural Science Foundation of China [51772285, 51572254]
- Fundamental Research Funds for the Central Universities
This study presents synthesis and characterizations of two novel curved nanographenes that strongly bind with fullerene C-60 to form photoconductive heterojunctions. Films of the self-assembled curved nanographene/fullerene complexes, which served as the photoconductive layer, generated a significant photocurrent under light irradiation. Gram-scale quantities of these curved nanographenes (TCR and HCR) as the crown sidewalls can be incorporated into a carbon nanoring to form molecular crowns, and the molecular structure of C-60@TCR is determined by single-crystal X-ray diffraction. The UV/Vis absorption and emission spectra, and theoretical studies revealed their unique structural features and photophysical properties. Time-resolved spectroscopic results clearly suggest fast photoinduced electron transfer process in the supramolecular heterojunctions.
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