期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 58, 期 16, 页码 5261-5265出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201814558
关键词
alkenes; cyclizations; hydrosilylation; isomerizations; palladium
资金
- JSPS KAKENHI [25708019, 18H01985, 15KT0069, 18H04271]
- Asahi Glass Foundation
- Japan Society for the Promotion of Science (JSPS) [14J04446]
- Grants-in-Aid for Scientific Research [25708019, 18H01985, 15KT0069, 14J04446, 18H04271] Funding Source: KAKEN
Sequential formation of distant bonds in organic molecules was achieved for the palladium-catalyzed hydrosilylation/cyclization of various 1,n-dienes by chain walking of the metal catalyst. The reaction was applicable to various 1,n-dienes, including a 1,13-diene, to form a cyclopentane ring as well as a carbon-silicon bond at a remote site. The use of nondissociative chain walking provides a fascinating strategy in organic synthesis to functiorudize distant parts of organic molecules, in a particular order, within a catalytic cycle by effectively moving the reactive center from a remote position.
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