期刊
ADVANCED FUNCTIONAL MATERIALS
卷 29, 期 13, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201809195
关键词
bismuth; high power density; multicore-shell; potassium-ion batteries; sodium-ion batteries
类别
资金
- National Key R&D Research Program of China [2018YFB0905400]
- National Natural Science Foundation of China [51622210, 51872277]
- Fundamental Research Funds for the Central Universities [WK3430000004]
- DNL cooperation Fund, CAS [DNL180310]
Bismuth (Bi) is an attractive material as anodes for both sodium-ion batteries (NIBs) and potassium-ion batteries (KIBs), because it has a high theoretical gravimetric capacity (386 mAh g(-1)) and high volumetric capacity (3800 mAh L-1). The main challenges associated with Bi anodes are structural degradation and instability of the solid electrolyte interphase (SEI) resulting from the huge volume change during charge/discharge. Here, a multicore-shell structured Bi@N-doped carbon (Bi@N-C) anode is designed that addresses these issues. The nanosized Bi spheres are encapsulated by a conductive porous N-doped carbon shell that not only prevents the volume expansion during charge/discharge but also constructs a stable SEI during cycling. The Bi@N-C exhibits unprecedented rate capability and long cycle life for both NIBs (235 mAh g(-1) after 2000 cycles at 10 A g(-1)) and KIBs (152 mAh g(-1) at 100 A g(-1)). The kinetic analysis reveals the outstanding electrochemical performance can be attributed to significant pseudocapacitance behavior upon cycling.
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