期刊
ADVANCED FUNCTIONAL MATERIALS
卷 29, 期 23, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201900712
关键词
anion exchange; continuous nanomanufacturing; in situ characterization; microfluidics; perovskite quantum dots
类别
资金
- UNC Research Opportunities Initiative (UNC-ROI) grant
- North Carolina State University
- Air Force Office of Scientific Research [FA9550-18-1-0331]
- State of North Carolina
- National Science Foundation [ECCS-1542015, DMR-1726294]
In an effort to produce the materials of next-generation photoelectronic devices, postsynthesis halide exchange reactions of perovskite quantum dots are explored to achieve enhanced bandgap tunability. However, comprehensive understanding of the multifaceted halide exchange reactions is inhibited by their vast relevant parameter space and complex reaction network. In this work, a facile room-temperature strategy is presented for rapid halide exchange of inorganic perovskite quantum dots. A comprehensive understanding of the halide exchange reactions is provided by isolating reaction kinetics from precursor mixing rates utilizing a modular microfluidic platform, Quantum Dot Exchanger (QDExer). The effects of ligand composition and halide salt source on the rate and extent of the halide exchange reactions are illustrated. This fluidic platform offers a unique time- and material-efficient approach for studies of solution phase-processed colloidal nanocrystals beyond those studied here and may accelerate the discovery and optimization of next-generation materials for energy technologies.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据