Grain boundary diffusion of 59Fe in high-purity copper

Grain boundary diffusion of iron in high purity polycrystalline copper is measured using the radiotracer technique and applying the Fe-59 isotope. At lower temperatures, T<949 K, the measurements are performed under Harrison's C-type kinetic regime and the grain boundary diffusion coefficient of Fe in Cu, D-gb, is determined, D-gb = 5.6.10(-6) x exp(-121kJmol(-1)/RT) m(2)/s. Unconventional penetration profiles are measured for Fe grain boundary diffusion in Cu at higher temperatures (>= 949 K) under the intended B-type kinetic regime, in fact formal C-type profiles are systematically observed instead. Molecular dynamics simulation with the literature Finnis-Sinclair type interatomic potentials [Ackland et al., Phil. Mag. A, 1997] discovered an unexpected response of Cu grain boundaries on a partial Fe coverage at temperatures above 900 K. A model of Fe penetration in polycrystalline Cu in such conditions is proposed, which explains the untypical shape of the penetration profiles. The combination of the B- and C- type grain boundary diffusion measurements predict a strong segregation of Fe in Cu with a low segregation enthalpy. (C) 2018 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.