Improved Stability of Metal Nanowires via Electron Beam Irradiation Induced Surface Passivation

Suppressing the corrosion of nanoscaled metal materials is a critical issue for various devices. Herein, we demonstrate the electron beam irradiation can be a simple and efficient method to realize silver/copper nanowires protection by transforming the original organic capping agents into dense carbonaceous shells. Single nanowire tests prove the significant stability improvement from 4 days to 20 days for silver nanowire and from 20 h to at least 1 week for copper nanowire. The comprehensive advantages such as solution/pollution-free and continuous process with high precision offer this method substantial potential applications in bottom-up assembled electronic and optoelectronic devices.