期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 358, 期 6, 页码 977-983出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201500844
关键词
cross-coupling reactions; homocoupling; Miyaura borylation; palladium; solvent-free reactions
资金
- RFBR [13-03-1224013 ofi m]
Solvent-free protocols for Miyaura borylation and the one-pot, two-step homocoupling of aryl halides are reported for the first time. Bis(di-benzylideneacetone) palladium(0) [Pd(dba)(2)] is an optimal source of palladium for Miyaura borylation, while for one-pot two-step homocoupling palladium(II) acetate [Pd(OAc)(2)] gives highest yields. Aryl bromides are coupled most efficiently using the DPEphos ligand. Chlorides are coupled using XPhos. The developed protocols are robust, versatile and easily reproducible on a large scale.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据