期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 358, 期 21, 页码 3435-3442出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201600500
关键词
fungicidal activity; fused polycycles; radical cascade reaction; trifluoromethylation
资金
- National Natural Science Foundation of China [21132003, 21421062, 21372131, 21672117]
- Specialized Research Fund for the Doctoral Program of Higher Education [20130031110017]
- Tianjin Natural Science Foundation [16JCZDJC32400]
A series of trifluoromethyl-containing heterocycles, like indene and dihydroquinolinone or dihydrocoumarin-fused tetracyclic compounds have been prepared using copper-catalyzed cascade reaction of benzene-tethered 1,7-enynes. A study of the mechanism indicated that radical trifluoromethylation and sequential 6-exo-dig/5-endo-trig bicyclization processes were involved in this protocol. More-over, some selected products showed certain fungicidal activities against 14 kinds of plant fungi which means that these functionalized tetracyclic compounds might be used in the agrochemical field.
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