期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 358, 期 13, 页码 2093-2099出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201600191
关键词
amination; arenes; CH functionalization; catalysis; hypervalent iodine
资金
- F. Hoffmann-La Roche Ltd.
- Spanish Ministry for Economy and Competitiveness
- FEDER [CTQ2014-56474R, SEV-2013-0319]
- ICREA Funding Source: Custom
1,2-Diiodobenzene is presented as an efficient catalyst precursor for the intermolecular amination of arenes under homogeneous conditions. N-Troc- and N-phthalimido-substituted methoxyamines serve as suitable nitrogen sources providing the corresponding aniline derivatives in up to 99% yield and with up to 66:1 regioselectivity. Key for this successful CN coupling protocol is the strained -oxo-bridged conformation of the bisiodine(III) catalyst, which induces unparalleled high reactivity.
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