4.8 Article

Reduced Intramolecular Twisting Improves the Performance of 3D Molecular Acceptors in Non-Fullerene Organic Solar Cells

期刊

ADVANCED MATERIALS
卷 28, 期 38, 页码 8546-8551

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201600997

关键词

high mobility; reduced intramolecular twisting; small-molecular acceptors; structural-property relationships; twisted 3D structures

资金

  1. National Basic Research Program of China (973 Program) [2013CB834701, 2014CB643501]
  2. Hong Kong Research Grants Council [T23-407/13 N, N_HKUST623/13, 606012]
  3. HKUST President's Office through SSTSP scheme [EP201]
  4. National Science Foundation of China (NSFC) [21374090, 21504066, 21534003, 51320105014, 51361165301]
  5. National Science Foundation of China [21273188]

向作者/读者索取更多资源

A small-molecular acceptor, tetraphenyl-pyrazine-perylenediimide tetramer (TPPzPDI 4), which has a reduced extent of intramolecular twisting compared to two other small-molecular acceptors is designed. Benefiting from the lowest extent of intramolecular twisting, TPPz-PDI 4 exhibits the highest aggregation tendency and electron mobility, and therefore achieves a highest power conversion efficiency of 7.1%.

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