4.8 Article

Ferroelectric-Enhanced Polysulfide Trapping for Lithium-Sulfur Battery Improvement

期刊

ADVANCED MATERIALS
卷 29, 期 6, 页码 -

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201604724

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资金

  1. National Natural Science Foundation of China [51674202, 51302219, 51521061, 51302172, 51472204]
  2. Natural Science Foundation of Shannxi Province [2015JM2045]
  3. Specialized Research Fund for the Doctoral Program of Higher Education of China [20136102120024]
  4. Fundamental Research Funds for the Central Universities [3102014JCQ01019, 3102015BJ(II)MYZ02]
  5. Shenzhen Key Laboratory of Special Functional Materials, Shenzhen University, China [T201504]

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A brand new polysulfide entrapping strategy based on the ferroelectric effect has been demonstrated for the first time. By simply adding the nano-ferroelectrics (BaTiO3 nanoparticles) into the cathode, the heteropolar polysulfides can be anchored within the cathode due to the internal electric field originated from the spontaneous polarization BaTiO3 nanoparticles, and thus significantly improving the cycle stability of Li-S batteries.

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