期刊
NATURE REVIEWS CHEMISTRY
卷 3, 期 1, 页码 15-34出版社
NATURE PUBLISHING GROUP
DOI: 10.1038/s41570-018-0059-x
关键词
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资金
- National Institutes of Health [1R35GM119457]
- Alfred P. Sloan Foundation
Low-valent early transition metals are often intrinsically highly reactive as a result of their strong propensity toward oxidation to more stable high-valent states. Harnessing these highly reducing complexes for productive reactivity is potentially powerful for C-C bond construction, organic reductions, small-molecule activation and many other reactions that offer orthogonal chemoselectivity and/or regioselectivity patterns to processes promoted by late transition metals. Recent years have seen many exciting new applications of low-valent metals through building new catalytic and/or multicomponent reaction manifolds out of classical reactivity patterns. In this Review, we survey new methods that employ early transition metals and invoke low-valent precursors or intermediates in order to identify common themes and strategies in synthesis and catalysis.
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