期刊
ADVANCED MATERIALS
卷 28, 期 37, 页码 8150-8155出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201506462
关键词
coordination polymers; crystal growth; microfluidics; out-of-equilibrium structures
类别
资金
- MINECO-Spain [MAT2012-30994, CTQ2011-16009-E]
- European Research Council under the European Union/ERC [615954]
- Swiss National Science Foundation (SNF) [200021_160174]
- ICN2
- Spanish MINECO through the Severo Ochoa Centers of Excellence Program [SEV-2013-0295]
- EPSRC [EP/M005178/1] Funding Source: UKRI
- ICREA Funding Source: Custom
- European Research Council (ERC) [615954] Funding Source: European Research Council (ERC)
- Engineering and Physical Sciences Research Council [EP/M005178/1] Funding Source: researchfish
A methodology that can be efficiently used to synthesize, isolate, and study out-of-equilibrium crystal structures employing controlled and diffusion-limited microfluidic environments is demonstrated. Unlike studies conducted with conventional mixing procedures in a flask, it is proven experimentally and with numerical simulations that microfluidic technologies can undoubtedly fine-tune reaction times and reagents concentration profiles; factors that enable out-of-equilibrium crystal forms to be obtained.
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