期刊
ADVANCED FUNCTIONAL MATERIALS
卷 26, 期 9, 页码 1428-1436出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201504695
关键词
-
类别
资金
- Natural Science Foundation of China [21501035, 21271055, 21471040, 21303030]
- China Postdoctoral Science Foundation [2015M570298]
- Fundamental Research Funds for the Central Universities (HIT, IBRSEM) [A.201410]
- Program for Innovation Research of Science in Harbin Institute of Technology [B201412, B201508]
Co3O4 anode materials exhibit poor conductivity and a large volume change, rendering controlling of their nanostructure essential to optimize their lithium storage performance. Carbon-doped Co3O4 hollow nanofibers (C-doped Co3O4 HNFs), for the first time are synthesized using bifunctional polymeric nanofibers as template and carbon source. Compared with undoped Co3O4 HNFs and solid Co3O4 NFs, C-doped Co3O4 HNFs feature a remarkably high specific capacity, excellent cycling stability, and superior rate capacity as anode materials for lithium-ion batteries. The superior performance of C-doped Co3O4 HNFs electrodes can be attributed to their structural features, which confer enhanced electron transportation and Li+ ion diffusion due to C-doping, and tolerance for volume change due to the 1D hollow structure. Density functional theory calculations provide a good explanation of the observed enhanced conductivity in C-doped Co3O4 HNFs.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据