期刊
ADVANCED FUNCTIONAL MATERIALS
卷 26, 期 24, 页码 4397-4404出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201600636
关键词
cobalt nanoparticles; bifunctional electrocatalysis; hydrogen evolution reaction; nitrogen-enriched graphene shells; oxygen reduction reaction; zinc-air batteries
类别
资金
- National Natural Science Foundation of China [51472173, 51522208]
- Natural Science Foundation of Jiangsu Province [BK20140302, SBK2015010320]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
- Collaborative Innovation Center of Suzhou Nano Science and Technology
There has been a continuous call for active, durable, and low-cost electrocatalysts for a range of energy applications. Among many different nonprecious metal based candidates, transition metal nanoparticles encapsulated in graphene layers have gained increasing attention over recent years. In this study, it is demonstrated that metallic cobalt nanoparticles sheathed by multilayered nitrogen-enriched graphene shells can be facilely prepared using cobalt-containing Prussian blue colloids as the single precursor. These metallic cobalt cores can be readily leached out by HCl treatment, resulting in hollow graphene spheres. Products with or without acid leaching exhibit great bifunctional activities for electrocatalytic oxygen reduction and hydrogen evolution in both alkaline and acidic electrolytes. Most importantly, it is found that the removal of the metallic cores does not deteriorate but rather enhances the electrocatalytic performance. Based on this and other experimental observations, Co-N-C moieties are proposed as the catalytically active sites. At last, it is shown that these catalysts can be employed as the air catalyst of primary zinc-air batteries with excellent current density, power density, and operation durability.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据