期刊
CHEMISTRYSELECT
卷 3, 期 41, 页码 11398-11405出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.201802490
关键词
Hydrodeoxygenation; Metal silicide; Ni-Al-LDHs; One-step CVD; Si-O-Al
资金
- National Natural Science Foundation of China [21373038, 21403026]
- China Postdoctoral Science Foundation [2015T80255]
- Natural Science Foundation of Liaoning Province in China [2015021014]
- Project Partenariats Hubert Curien (PHC) Cai Yuanpei - French Embassy in China
- China Scholarship Council
A bifunctional Ni2Si/SiO2-Al2O3 catalyst was prepared by one-step chemical vapor deposition (CVD), and used for hydrode-oxygenation (HDO) of diphenyl ether (DPE). During the one-step CVD process, metallic Ni species as the HDO active sites were isolated by intermetallic modification of Si atoms and partial electron transferred from Ni to Si, as inferred by XRD, XPS, and theoretical calculation. Furthermore, the characterization results revealed that the acidity and structure of Al2O3 were tuned due to the formation of Al-O-Si bonds. Consequently, compared with Ni/Al2O3 catalyst, the Ni2Si/SiO2-Al2O3 catalyst showed a higher benzene selectivity (60% vs 47%), O-free products selectivity at the similar conversion of DPE, and high stability for the HDO of DPE. This work provides insight for design of bifunctional catalysts with specific catalytic properties by one-step CVD method.
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