4.5 Article

Green Conversion of Microalgae into High-Performance Sponge-Like Nitrogen-Enriched Carbon

期刊

CHEMELECTROCHEM
卷 6, 期 3, 页码 646-652

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/celc.201801272

关键词

microalgae; one-step activation; sponge-like carbon; nitrogen enriched; supercapacitor

资金

  1. National Science Fund for Distinguished Young Scholars [51725603]
  2. National Natural Science Foundation of China [51476142, 51661145011]
  3. National Science and Technology Supporting Plan Through Contract [2015BAD15B06]

向作者/读者索取更多资源

The selective conversion of biomass into high-value carbon materials has recently been attracting increasing attraction. In this study, a microalga with a high nitrogen content, namely Spirulina platensis, was used as both the carbon and nitrogen precursors in the synthesis of sponge-like nitrogen-enriched carbon materials through a one-step activation method with NaHCO3 as a green activator. The sponge-like nitrogen-enriched carbon materials obtained at different activation temperatures were systematically characterized by using SEM, N-2 adsorption-desorption, XRD, Raman, and XPS techniques. A series of tests were performed to investigate the electrochemical characteristics of the obtained carbon materials to determine their potential use as supercapacitors. The results show that sponge-like nitrogen-enriched carbon activated at 700 degrees C, which has a large BET surface area of 865 m(2)/g and a high nitrogen content of 7.5 wt%, gave the largest specific capacitance of 234.0 F/g at a current density of 1 A/g in a 6 M KOH electrolyte.

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