期刊
ADVANCED OPTICAL MATERIALS
卷 7, 期 7, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adom.201801536
关键词
aromatic diketone; multiple resonance effect; organic light-emitting diodes; TADF emitter; thermally activated delayed fluorescence
资金
- National Natural Science Foundation of China [61575136, 21572152, 51873139]
- National Key R&D Program of China [2016YFB0400703]
- Collaborative Innovation Center of Suzhou Nano Science and Technology (Nano-CIC)
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
- 111 Project
- Joint International Research Laboratory of Carbon-Based Functional Materials and Devices
Multiple resonances induced thermally activated delayed fluorescence (MR-TADF) has great advantages in high color purity display. Up to now, current MR-TADF emitters are only based on the boron-nitrogen-containing fragment. Reported herein is a novel class of MR-TADF emitter, quinolino[3,2,1-de]acridine-5,9-dione (QAO), realized by the opposite resonance effect of the carbonyl and the nitrogen atoms, which is also the smallest TADF emitter reported so far. The QAO-based pure blue organic light-emitting diode achieves a maximum external quantum efficiency (EQE(max)) of 19.4% with a small full width at half maximum of 39 nm. Moreover, tert-butyl modified QAO can be employed as an efficient electron acceptor to construct an efficient yellow-green evaporation and solution process feasible TADF emitter, 7-(tert-butyl)-3,11-bis(9,9-dimethylacridin-10(9H)-yl)quinolino[3,2,1-de]acridine-5,9-dione (QAO-DAd), with significantly improved performance as compared to the previous flexible diketone-based emitters.
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