期刊
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷 7, 期 3, 页码 3602-3613出版社
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.8b06271
关键词
Ionic liquids; Epoxy network; Polymerization reaction mechanisms; Ionic conductivity
资金
- Ministere de l'Enseignement Superieur et de la Recherche (MESR)
- Groupement de Recherches Liquides Ioniques et PolymereS [5223]
In this work, new (multi)functional-dedicated polymer materials were designed and processed from the copolymerization between novel imidazolium ionic liquid monomer (ILM) with a conventional polyetheramine denoted Jeffamine D230. First, a facile and robust synthetic route was investigated in order to design polyfunctional imidazolium monomers bearing an aromatic ring and two epoxy functions at the end of aliphatic chains. Then, the main mechanisms of epoxy opening leading to polymerization with different kinetics were modeled through the reaction between a monofunctional epoxy and aliphatic mono- and diamines by using in situ NMR spectroscopy. Finally, the monomer molecular structure network architecture-physical properties relationships of the resulting IL-modified epoxy networks were investigated. As a consequence, epoxy networks with a glass transition temperature of 55 degrees C and with enhanced properties such as thermal stability (>300 degrees C), storage modulus of 700 MPa at room temperature, and an ionic conductivity (4 X 10(-4) S m(-1) for 70 degrees C) combined with an hydrophobic character of their surface (33 mJ m(-2)) were prepared.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据