期刊
POLYMERS
卷 11, 期 1, 页码 -出版社
MDPI
DOI: 10.3390/polym11010147
关键词
perovskite solar cells; surface morphology; PCBM; doping
资金
- National Key Basic Research Program of China (973 Program) [2015CB932203]
- National Natural Science Foundation of China [61874058, 51861145301, 61376023]
- Priority Academic Program Development Fund of Jiangsu Higher Education Institutions (PAPD)
- Jiangsu Shuanchuang Team award
The commonly used electron transport material (6,6)-phenyl-C61 butyric acid methyl ester (PCBM) for perovskite solar cells (PSC) with inverted planar structures suffers from properties such as poor film-forming. In this manuscript, we demonstrate a simple method to improve the film-forming properties of PCBM by doping PCBM with poly(9,9-dioctylfluorene-co-benzothiadiazole) (F8BT) as the electron transport layer (ETL), which effectively enhances the performance of CH3NH3PbI3 based solar cells. With 5 wt % F8BT in PCBM, the short circuit current (J(SC)) and fill factor (FF) of PSC both significantly increased from 17.21 +/- 0.15 mAcm(-2) and 71.1 +/- 0.07% to 19.28 +/- 0.22 mAcm(-2) and 74.7 +/- 0.21%, respectively, which led to a power conversion efficiency (PCE) improvement from 12.6 +/- 0.24% to 15 +/- 0.26%. The morphology investigation suggested that doping with F8BT facilitated the formation of a smooth and uniform ETL, which was favorable for the separation of electron-hole pairs, and therefore, an improved performance of PSC.
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