期刊
MATERIALS
卷 11, 期 11, 页码 -出版社
MDPI
DOI: 10.3390/ma11112206
关键词
sodium-ion batteries; Na2Ti3O7; F-doping; electronic conductivity
类别
资金
- National Natural Science Foundation of China [51672029, 51372271, U1361119, 61503124]
- National Key R & D Project from Ministry of Science and Technology, China [2016YFA0202702]
- Natural Science Foundation of Henan Province (General Program) [162300410119, 162300410115]
- Special Medical Project of Henan Polytechnic University [NSFRF1621]
The effects of fluorine (F) doping on the phase, crystal structure, and electrochemical performance of Na2Ti3O7 are studied by X-ray diffraction (XRD), scanning electron microscopy (SEM), and electrochemical measurements. F-doping does not change the crystal structure of NTO, although it has an effect on the morphology of the resultant product. As an anode material for sodium-ion batteries, the specific capacity of Na2Ti3O7 exhibits a 30% increase with F-doping owing to the improved sodium ion diffusion coefficient. F-doped Na2Ti3O7 also displays an enhanced rate capability and favourable cycling performance for more than 800 cycles.
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