期刊
ADVANCED ENERGY MATERIALS
卷 8, 期 33, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.201802195
关键词
anatase facet engineered photocatalysis; facet electronic structure; facet induced vectorial charge carrier separation; photoelectron spectroscopy
类别
资金
- Erasmus Mundus Joint Doctoral program International Doctoral School in Functional Materials for Energy, Information Technology, and Health (Shun Kashiwaya fellowship)
- French-German University (UFA Doctoral College in Functional Materials for Energy and Information Technology)
Single crystalline anatase is used to prepare well defined (001) and (101) surfaces in ultrahigh vacuum (UHV) in different states: sputtered, annealed, stoichiometric, and oxidized. The electronic properties of the well-defined surfaces are investigated by X-ray photoelectron spectroscopy and ultraviolet photoelectron spectroscopy after UHV transfer. The Fermi level of (001) facets for all applied surface conditions is lower than that of the (101) facets by 150-450 meV. The energy difference leads to a potential difference (band bending) at the interface between the (101) and (001) facets, resulting in the migration of photogenerated electrons and holes to different directions namely to the (101) and (001) facets, respectively. Photoelectron spectroscopy measurements clearly indicate for the first time that differences in the surface electronic structure and related potential of different facets explain a vectorial electron-hole pair separation to different reaction sites providing design criteria for enhanced photocatalysis.
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