期刊
ACS CATALYSIS
卷 9, 期 2, 页码 890-894出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.8b03752
关键词
biocatalysis; formate dehydrogenase; hydrogen peroxide formation; oxyfunctionalization; peroxygenases; photocatalysis
资金
- Netherlands Organisation for Scientific Research through a VICI grant [724.014.003]
Peroxygenases require a controlled supply of H2O2 to operate efficiently. Here, we propose a photocatalytic system for the reductive activation of ambient O-2 to produce H2O2 which uses the energy provided by visible light more efficiently based on the combination of wavelength-complementary photosensitizers. This approach was coupled to an enzymatic system to make formate available as a sacrificial electron donor. The scope and current limitations of this approach are reported and discussed.
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