期刊
ACS CATALYSIS
卷 8, 期 12, 页码 10977-10984出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.8b02839
关键词
ammonia synthesis; heterogeneous catalyst; CaH2; transformed BaO; ruthenium
资金
- Accelerated Innovation Research Initiative Turning Top Science and Ideas into High-Impact Values (ACCEL) program of the Japan Science and Technology Agency (JST)
- Ministry of Education, Culture, Science, Sports, and Technology (MEXT) of Japan [18H05251]
- Grants-in-Aid for Scientific Research [18H05251] Funding Source: KAKEN
We report that a simple mixture of BaO and CaH2 powders with ruthenium nanoparticles acts as an effective heterogeneous catalyst for low-temperature ammonia synthesis with a very small activation energy (41 kJ mol(-1)). The high catalytic performance of this material is not due to either the original CaH2 or BaO particles but to BaO transformed by reaction with CaH2. The transformed BaO contains BaH2, a stable and strong electron-donating material that facilitates a reversible hydrogen storage-release reaction and significantly enhances electron donation to Ru, which results in high catalytic performance.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据