期刊
TETRAHEDRON LETTERS
卷 60, 期 4, 页码 390-396出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2018.12.064
关键词
Visible light; Alkylation; Benzothiazoles; N,N-Dimethylamides; Eosin Y; K2S2O8
资金
- National Natural Science Foundation of China [30900959]
- Natural Science Foundation of Zhejiang Province [LY17C140003]
Eosin Y/K2S2O8 catalyzed C2-alkylation reactions of benzothiazoles with N,N-dimethylamides under visible light have been developed. The reactions completed smoothly in the presence of Eosin Y as the photocatalyst and K2S2O8 as the oxidant under solvent-free conditions in open air. This green and simple method provides an alternative route for the synthesis of C2-alkylation of benzothiazoles and tolerates a number of functional groups to afford moderate to excellent yields. (C) 2018 Elsevier Ltd. All rights reserved.
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