期刊
TETRAHEDRON
卷 74, 期 48, 页码 6939-6945出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2018.10.022
关键词
Ring-expansion; Furans; Cyclopentanones; Pinacol rearrangement
资金
- National Program on Key Research Project [2016YFA0602900]
- National Natural Science Foundation of China [21572068, 21871094]
- Science and Technology Program of Guangzhou, China [201707010057]
- Guangdong Natural Science Foundation [2017A030312005]
- Science and Technology Planning Project of Guangdong Province, China [2017A020216021, 2016A020210082, 2014A020221035]
A BINOL-phosphoric acid-catalyzed furylogous Pinacol rearrangement is developed. This reaction produces spiro cyclopentanone in good yields under mild conditions. The enantioselective version of this reaction is also investigated using chiral phosphoric acid (CPA) as the catalyst. (C) 2018 Published by Elsevier Ltd.
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