期刊
SYNTHETIC COMMUNICATIONS
卷 48, 期 22, 页码 2912-2922出版社
TAYLOR & FRANCIS INC
DOI: 10.1080/00397911.2018.1524493
关键词
3-Acyloxyindoles; cobalt catalysis; C-H acyloxylation; C3-selective; indoles; tert-butyl peresters
资金
- National Natural Science Foundation of China [21562052, 21462055]
- Guizhou Provincial Department of Science and Technology [LH[2014]7547, LH[2014]7554]
- 15851 Talent Project Funding of Zunyi city [201423]
- National First-Rate Construction Discipline of Guizhou Province (Pharmacy) [YLXKJS-YX-04]
- Fifth Batch of Talent Base in Guizhou Province
A Co(II)-catalyzed direct C3-selective C-H acyloxylation of indoles has been realized with tert-butyl peresters serving as both an acyloxy source and an oxidant. This reaction features highly C3 regioselectivity and good functional group tolerance, which provides a convenient and versatile approach to the construction of valuable 3-acyloxyindoles in moderate to excellent yields. [GRAPHICS] .
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