期刊
SYNTHETIC COMMUNICATIONS
卷 48, 期 19, 页码 2539-2544出版社
TAYLOR & FRANCIS INC
DOI: 10.1080/00397911.2018.1511999
关键词
Aluminum carbenoids; cyclopropanation; cyclopropyl-allyl rearrangement; fulvenes; polycyclopropanes; spiro[2,4]hepta-4,6-diene
资金
- Presidium of the Russian Academy of Sciences [38]
- Ministry of Science and Education of the Russian Federation [NSh-5240.2018.3]
The reaction of Et3Al/CH2I2 reagent with cyclopropanated spiro[2.4]-hepta- 4,6-diene and 6-substituted fulvenes in CH2Cl2 was found to lead to the selective formation of rearrangement products through sequential cyclopropyl-allyl rearrangement and cyclopropanation.
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