期刊
SYNTHESIS-STUTTGART
卷 51, 期 2, 页码 303-333出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0037-1610329
关键词
acylation; photoredox catalysis; acyl radicals; visible light; single-electron transfer; oxidation; reduction; cross-coupling
资金
- National Institute of General Medical Sciences [R35GM119652]
Visible-light photoredox catalysis enables easy access to acyl radicals under mild reaction conditions. Reactive acyl radicals, generated from various acyl precursors such as aldehydes, -keto acids, carboxylic acids, anhydrides, acyl thioesters, acyl chlorides, or acyl silanes, can undergo a diverse range of synthetically useful transformations, which were previously difficult or inaccessible. This review summarizes the recent progress on visible-light-driven acyl radical generation using transition-metal photoredox catalysts, metallaphotocatalysts, hypervalent iodine catalysts or organic photocatalysts. 1 Introduction 2 The Scope of This Review 3 Aldehydes as a Source of Acyl Radicals 4 -Keto Acids as a Source of Acyl Radicals 5 Carboxylic Acids as a Source of Acyl Radicals 6 Anhydrides as a Source of Acyl Radicals 7 Acyl Thioesters as a Source of Acyl Radicals 8 Acyl Chlorides as a Source of Acyl Radicals 9 Acyl Silanes as a Source of Acyl Radicals 10 Conclusions and Future Outlook
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据